EXIDE CORP -- ALL LEAD ACID BATTERIES -- 6140-01-041-0264
===================== Product Identification ===================== Product ID:ALL LEAD ACID BATTERIES MSDS Date:05/01/1991 FSC:6140 NIIN:01-041-0264 === Responsible Party === Company Name:EXIDE CORP Address:9176 RED BRANCH RD City:COLUMBIA State:MD ZIP:21045-2059 Country:US Info Phone Num:301-596-2680 Emergency Phone Num:301-596-2680 CAGE:90660 === Contractor Identification === Company Name:ENERSYS INC Address:8306PATUXENT RANGE RS SUITE 103 Box:City:JESSUP State:MD ZIP:20794-8609 Country:US Phone:301-381-8500 OR 215-378-0757 CAGE:90660 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD (SARA III) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: 60% % Other REC Limits:NONE SPECIFIED OSHA PEL:0.05 MG/M3;1910.1025 ACGIH TLV:0.15 MG/M3;DUST 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ANTIMONY (SARA III) CAS:7440-36-0 RTECS #:CC4025000 Fraction by Wt: 2% % Other REC Limits:NONE SPECIFIED OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG SB/M3; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ARSENIC (SARA III) CAS:7440-38-2 RTECS #:CG0525000 Fraction by Wt: 0.2% % Other REC Limits:NONE SPECIFIED OSHA PEL:0.5 MG/M3 (AS) ACGIH TLV:0.01,A1 MG/M3; 9394 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:CALCIUM, METAL CAS:7440-70-2 RTECS #:EV8040000 Fraction by Wt: 0.2% % Other REC Limits:NONE SPECIFIED Ingred Name:TIN CAS:7440-31-5 RTECS #:XP7320000 Fraction by Wt: 0.2% % Other REC Limits:NONE SPECIFIED OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9192 Ingred Name:SULFURIC ACID (SARA III) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 10-30% Other REC Limits:NONE SPECIFIED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION:VAPORS OR MIST MAY CAUSE SEVERE RESPIRATORY IRRITATION. INHALATION OF DUST OR LEAD DUST OR FUMES MAY CAUSE IRRATION OF UPPER RESPIRATORY TRACT AND LUNGS. INGESTION; MAY CAUSE SEVERE IRRITAT ION OF MOUTH, THROAT, ESOPHAGUS AND STOMACH AND MAY CAUSE ABDOMINAL PAIN, NAUSEA, VOMITING, DIARRHEA AND CRAMPS. Explanation of Carcinogenicity:PRODUCT CONTAINS NO INGREDIENTS CURRENTLY CLASSIFIED AS CARCINOGENIC BY NTP, IARC OR OSHA. Effects of Overexposure:SEVERE SKIN IRRITATION, DAMAGE TO CORNEA, UPPER RESPIRATORY IRRITATION, HEADACHE, FATIGUE, ABDOMINAL PAIN, LOSS OF APPETITE, MUSCULAR ACHES AND WEAKNESS, SLEEP DISTURBANCES AND IRRITABILITY. EROSION O F TOOTH ENAMEL, INFLAMMATION OF NOSE, THROAT AND BRONCHIAL TUBES, ANEMIA, NEUROPHATY, PARTICULARLY OF THE MOTOR NERVES. Medical Cond Aggravated by Exposure:LUNG DAMAGE AND AGGRAVATED PULMONARY CONDITIONS, SKIN DISEASE AND SOME FORMS OF KIDNEY, LIVER AND NEUROLOGIC DISEASE MAY BE AGGRAVATED BY EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE, GARGLE, WASH NOSE AND LIPS. IF BREATHING IS DIFFICULT GIVE OXYGEN. CONSULT A PHYSCIAN. INGESTION: GIVE LARGE QUANTITIES OF WATER, DO NOT INDUCE VOMITING. CALL A PHYSC IAN. SKIN: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES, REMOVE ALL CONTAMINATED CLOTHING. EYES: FLUSH IMMEDIATELY WITH WATER FOR 15 MINUTES. CONSULT A DOCTOR. ===================== Fire Fighting Measures ===================== Lower Limits:4.1 % Upper Limits:74.2 % Extinguishing Media:CO2, FOAM, DRY CHEMICAL, HALOGEN Fire Fighting Procedures:IF BATTERIES ARE ON CHARGE, SHUT OFF POWER. USE POSITIVE PRESSURE, SCBA, WATER APPLIED TO ELECTROLYTE GENERATES HEAT AND MAY SPLATTER. Unusual Fire/Explosion Hazard:HIGHLY FLAMMABLE HYDGROGEN GAS IS GENERATED DURING CHARGING AND OPERATING OF BATTERIES. KEEP HEAT AND SPARKS AWAY. ================== Accidental Release Measures ================== Spill Release Procedures:STOP FLOW OF MATERIAL, CONTAIN/ABSORB SPILLS WITH DRY SAND, EARTH, OR VERMIVULITE. DO NOT USE COMBUSTIBLE MATERIALS. DO NOT DISCHARGE UNNEUTRALIZED ACID TO SEWER. Neutralizing Agent:LIME, SODA ASH OR SODIUM BICARBONATE. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL WELL VENTILATED AREA WITH IMPERVIOUS SURFACES AND ADEQUATE CONTAINMENT IN THE EVENT OF SPILLS, ADEQUATE WATER SUPPLY FOR SPILL CONTROL. Other Precautions:NONE GIVEN ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN CONCENTRATION OF SULFURIC ACID MIST ARE KNOWN TO EXCEED PEL USE NIOSH OR MSHA APPROVED RESPIRATORY PROTECTION. Ventilation:LOCAL Protective Gloves:ACID RESISTANT W/ELBOW LENGTH GAUNTLET Eye Protection:CHEMICAL GOGGLES OR FACE SHIELD Other Protective Equipment:ACID RESISTANT APRON. ACID RESISANT CLOTHING IF CONDITION WARRANT. Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT AND BEFORE EATING DRINKING OR SMOKING. Supplemental Safety and Health IN AREAS WHERE SULFURIC ACID IS HANDLED IN CONCENTRATIONS GREATER THAN 1% EMERGENCY EYE WASHES AND SHOWERS SHOULD BE PROVIDED WITH UNLIMITED WATER SUPPLY. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:203F,95C Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:10 MMHG Vapor Density:>1 Spec Gravity:1.230-1.350 Evaporation Rate & Reference:<1 Solubility in Water:100% Appearance and Odor:MANUFACTURED ARTICE NO ODOR Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES COMBUSTIBLES AND ORGANIC MATERIALS MAY CAUSE FIRE AND EXPLOSION. ALSO REACTS WITH STRONG REDUCING AGENTS. Stability Condition to Avoid:PROLONGED OVERCHARGE, SOURCES OF IGNITION. Hazardous Decomposition Products:SULFURIC ACID:SULFUR TRIOXIDE, CARBON MONOXIDE, SULFURIC ACID MIST, SULFUR DIOXIDE, HYDROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE NEUTRALIZED SLURRY INTO SEALED CONTAINERS AND DISPOSE OF AS HAZARDOUS WASTE AS APPLICABLE. LARGE WATER-DILUTED SPILLS, AFTER NEUTRALIZATIOM AND TESTING SHOULD BE MANAGED IN ACCORDANCE WITH APPRO VED LOCAL STATE AND FEDERAL REQUIREMENTS. 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